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Lightning is five times hotter than the Sun's surface.

A lightning channel heats the air to around 30,000 °C, roughly five times the Sun's surface temperature. The air expands explosively; that shock wave is the thunder you hear. Light reaches you instantly, sound takes about three seconds per kilometer. Worldwide there are some 40 to 50 flashes every second; only about one in four reaches the ground.

Useful: Seconds between flash and thunder divided by three gives the distance in kilometers.

Source: en.wikipedia.org

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